Homoleptic ruthenium(III) chalcogenolates: a single precursor to metal chalcogenide nanoparticles catalyst.

نویسندگان

  • Sharon Lai-Fung Chan
  • Kam-Hung Low
  • Gary Kwok-Ming So
  • Stephen Sin-Yin Chui
  • Chi-Ming Che
چکیده

Eight homoleptic metal(III) arylchalcogenolate polymers [M(EPh-p-X)(3)](n) (M = Ru, Cr, and Mo) were characterized by PXRD. Structural solution of [Ru(SPh-p-tBu)(3)](n)1 was achieved by Rietveld refinement of the PXRD data. Pyrolysis of [Ru(SePh)(3)](n)4 produced nanostructured RuSe(2), which selectively catalyzed the reduction of nitro compounds in the presence of other functionalities.

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عنوان ژورنال:
  • Chemical communications

دوره 47 31  شماره 

صفحات  -

تاریخ انتشار 2011